Quotulatiousness

April 4, 2013

April 1st meets scientific illiteracy in Florida

Filed under: Humour, Media, USA — Tags: , , , — Nicholas @ 00:01

Did you know that there is dihydrogen monoxide streaming out of the water taps in Fort Myers, Florida? Apparently a lot of radio listeners thought this was a very bad thing:

Florida country radio morning-show hosts Val St. John and Scott Fish are currently serving indefinite suspensions and possibly worse over a successful April Fools’ Day prank. They told their listeners that “dihydrogen monoxide” was coming out of the taps throughout the Fort Myers area. Dihydrogen monoxide is water.

The popular deejays are mainly in all this trouble (potentially of a felony level) because their listeners panicked so much — about the molecular makeup of their drinking water, however unwittingly — that Lee County utility officials had to issue a county-wide statement calming the fears of chemistry challenged Floridians.

February 15, 2013

A useful bit of perspective over Whinnygate

Filed under: Europe, Food, Health — Tags: , — Nicholas @ 11:35

It’s reasonable to be concerned that your hamburger may once have raced in the Grand National, but worries about chemical contamination from the horse meat are almost certainly overblown. In fact, your health might be more at risk from the burger itself:

There is reasonable public outrage at possible criminal conspiracies to adulterate meat products with horsemeat, and additional concerns raised about the presence of the anti-inflammatory known as bute.

While not in any way questioning this concern about adulteration with a chemical compound, it is helpful to get a sense of magnitude. When bute was given as a human medicine, it was reported to be associated with a serious adverse reaction in 1 in 30,000 (over a whole course of treatment), but at a dose giving concentrations at least 4,000 times that arising from eating a diet of horse meat – see the excellent information from the Science Media Centre

So making all sorts of heroic assumptions about there being a linear-no-threshold response, we might very roughly assign a pro-rata risk of a serious event as 1 in 100,000,000 per burger.

January 10, 2013

QotD: The mild, quiet, unassuming world of high-nitrogen compounds

Filed under: Humour, Quotations, Science — Tags: , — Nicholas @ 00:02

When we last checked in with the Klapötke lab at Münich, it was to highlight their accomplishments in the field of nitrotetrazole oxides. Never forget, the biggest accomplishment in such work is not blowing out the lab windows. We’re talking high-nitrogen compounds here (a specialty of Klapötke’s group), and the question is not whether such things are going to be explosive hazards. (That’s been settled by their empirical formulas, which generally look like typographical errors). The question is whether you’re going to be able to get a long enough look at the material before it realizes its dream of turning into an expanding cloud of hot nitrogen gas.

It’s time for another dispatch from the land of spiderweb-cracked blast shields and “Oh well, I never liked that fume hood, anyway”. Today we have a fine compound from this line of work, part of a series derived from N-amino azidotetrazole. The reasonable response to that statement is “Now hold it right there”, because most chemists will take one look at that name and start making get-it-away-from-me gestures. I’m one of them. To me, that structure is a flashing red warning sign on a dead-end road, but then, I suffer from a lack of vision in these matters.

But remember, N-amino azidotetrazole (I can’t even type that name without wincing) is the starting material for the work I’m talking about today. It’s a base camp, familiar territory, merely a jumping-off point in the quest for still more energetic compounds. The most alarming of them has two carbons, fourteen nitrogens, and no hydrogens at all, a formula that even Klapötke himself, who clearly has refined sensibilities when it comes to hellishly unstable chemicals, calls “exciting”. Trust me, you don’t want to be around when someone who works with azidotetrazoles comes across something “exciting”.

Derek Lowe, “Things I Won’t Work With: Azidoazide Azides, More Or Less”, In the Pipeline, 2013-01-09

May 13, 2012

Eating experience mediated by the metal in your cutlery

Filed under: Food, Science — Tags: — Nicholas @ 10:41

An interesting post at Edible Geography on a recent taste-test:

Previous studies have suggested that some metals in solution actually produce a “metallic” taste — a distinct sensation to add to the standard sweet, sour, bitter, salty, and umami descriptors. This is still a controversial idea in the world of sensory science, where umami took nearly a century to gain official recognition, although among water engineers iron and copper are known to affect the taste and consumer acceptability of drinking water.

In any case, Laughlin, Miodownik, et al. wanted to test the taste of solid metals. They speculated that metals such as copper and zinc that were less stable, and thus more likely to acquire electrons, would taste more metallic because their atoms would form a solution in human saliva more readily. Their blindfolded spoon-eaters (with each lick of a spoon, as Miodownik explained to Dunlop, we are not just tasting metal, but actually “consuming ‘perhaps a hundred billion atoms’”) confirmed the scientists’ suspicions, rating the less chemically active gold and chrome spoons as the most pleasant and sweet tasting, and the more reactive copper and zinc as bitter, strong, and metallic tasting.

[. . .]

Using four samples of Tesco extra thick double cream with sugar, lemon juice (sour), lemon pith (bitter), and salt added, four teaspoons of identical weight, electroplated in stainless steel, copper, zinc, and gold, and thirty human guinea-pigs, Laughlin, Miodownik, Charles Spence, and Betina Piqueras-Fiszman concluded that “cutlery coated with different materials really does taste different,” and, what’s more, that these differences are significant enough to “influence the perception of taste and pleasantness of food consumed from them.”

The more metallic tasting copper and zinc spoons enhanced or added bitter qualities to each of the creams, as expected, but — to the scientists’ surprise — they also boosted its dominant taste. In other words, the sweet cream was perceived as being slightly sweeter when eaten from a copper or zinc spoon than a gold or stainless steel spoon, while the salty cream tasted saltier.

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